Sanitary Control of Flexible PVC films Commercialized in the State of Rio de Janeiro

Authors

  • Fabio Silvestre Bazilio Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ Author
  • George Leon Machado Barros Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ Author
  • Shirley de Mello Pereira Abrantes Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ Author

DOI:

https://doi.org/10.3395/2317-269x.00250

Keywords:

Migration, Fatty foods, Di-(2-ethylhexyl) adipate, Di-(2-ethylhexyl) phthalate, Gas Chromatography

Abstract

n total, 37 samples of flexible PVC films were analyzed for specific migration of di-(2-ethylhexyl) phthalate (DEHP) and di-(2-ethylhexyl) adipate (DEHA) from packaging to fatty foods, using simulant. The Resolution n. 17, of March 17, 2008, published by ANVISA, establishes specific migration limits for DEHP in 1.5 mg kg−1 of simulant and for DEHA in 18 mg kg−1 of simulant. The migration test was performed through contact between a 1-dm2 PVC film cutout and 100 mL of food simulant, ethanol 95% (v/v), for 48 h at 20ºC. The migrations of DEHP and DEHA were determined by gas chromatography with a flame ionization detector and a fused silica column internally coated with a stationary phase consisting of 5% phenylmethylsilicone. The results from the samples showed specific migration of DEHP ranging between not detectable (< 0.35 mg kg−1) and 304 mg kg−1 of food simulant and between not detectable (< 2.23 mg kg−1) and 231 mg kg−1 of food simulant for DEHA. Among the tested samples, 95% had results above the limit established by legislation.

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Author Biographies

  • Fabio Silvestre Bazilio, Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ
    Setor de Contaminantes Orgânicos - Departamento de Química - INCQS - FioCruz
  • George Leon Machado Barros, Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ
    Setor de Contaminantes Orgânicos - Departamento de Química - INCQS - FioCruz
  • Shirley de Mello Pereira Abrantes, Departamento de Química, Instituto Nacional de Controle de Qualidade em Saúde, Fundação Oswaldo Cruz (INCQS/Fiocruz), Rio de Janeiro, RJ
    Setor de Contaminantes Orgânicos - Departamento de Química - INCQS - FioCruz

Published

2015-08-26

Issue

Section

Articles

How to Cite

Sanitary Control of Flexible PVC films Commercialized in the State of Rio de Janeiro. (2015). Health Surveillance under Debate: Society, Science & Technology , 3(3), 78-84. https://doi.org/10.3395/2317-269x.00250